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Solutions | Chemistry | Full marathon | Class 12 | CBSE 2024 |🔥 Shimon Sir
29, Mar, 2025
Types of Solutions
A solution is a homogeneous mixture of two or more substances. It consists of a solute (substance being dissolved) and a solvent (substance in which the solute is dissolved). Solutions can exist in different states based on the phase of solute and solvent.
1. Gaseous Solutions
  • The solvent is a gas, and the solute can be a gas, liquid, or solid.
  • Examples:
  • Gas in Gas: Air (oxygen and nitrogen).
  • Liquid in Gas: Water vapor in air (humidity).
  • Solid in Gas: Camphor vapor in air.
2. Liquid Solutions
  • The solvent is a liquid, and the solute can be a gas, liquid, or solid.
  • Examples:
  • Gas in Liquid: Carbonated drinks (CO₂ dissolved in water).
  • Liquid in Liquid: Alcohol in water (ethanol-water solution).
  • Solid in Liquid: Salt in water (NaCl solution).
3. Solid Solutions
  • The solvent is a solid, and the solute can be a gas, liquid, or solid.
  • Examples:
  • Gas in Solid: Hydrogen in palladium (used for hydrogen storage).
  • Liquid in Solid: Mercury in silver (dental amalgam).
  • Solid in Solid: Alloys like brass (copper and zinc) or steel (iron and carbon).

Expression of Concentration of Solutions of Solids in Liquids

The concentration of a solution refers to the amount of solute present in a given quantity of solvent or solution. It can be expressed in various ways, depending on the requirements of a particular application.

Different Ways to Express Concentration

  • Mass Percentage (% w/w):
    Mass % = (Mass of solute / Mass of solution) × 100

    It represents the mass of solute in 100 grams of solution.

  • Volume Percentage (% v/v):
    Volume % = (Volume of solute / Volume of solution) × 100

    It is used when both solute and solvent are liquids.

  • Mass by Volume Percentage (% w/v):
    Mass/Volume % = (Mass of solute in grams / Volume of solution in mL) × 100

    Commonly used in medical and pharmaceutical applications.

  • Molarity (M):
    M = Moles of solute / Volume of solution in liters

    Expresses concentration in terms of moles of solute per liter of solution.

  • Molality (m):
    m = Moles of solute / Mass of solvent in kg

    Used when temperature variations affect the solution volume.

  • Normality (N):
    N = Number of gram equivalents of solute / Volume of solution in liters

    It depends on the type of reaction and is used in acid-base and redox reactions.

  • Parts per Million (ppm):
    ppm = (Mass of solute / Mass of solution) × 10⁶

    Used for very dilute solutions, such as pollutants in air or water.

  • Parts per Billion (ppb):
    ppb = (Mass of solute / Mass of solution) × 10⁹

    Used for extremely low concentrations, such as contaminants in drinking water.

  • Mole Fraction (χ):
    χA = nA / (nA + nB)

    Where nA and nB are the moles of solute and solvent, respectively.

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